From biomass to biofuel – Why on-site enzyme production is the future

Biorefineries that convert residual biomass into useful fuels and chemicals are starting to spring up across the globe. No surprise given their ability to turn previously worthless waste into valuable end products such as fuel for vehicles.

There is, however, a problem and it all comes down to the humble yet powerful cellulase enzymes used to turn biomass into sugars. These enzymes are produced at only a few key facilities in North America and Europe before being shipped to biorefineries around the world. This means they are expensive, which creates a significant cost barrier to the broader deployment of biorefinery concepts.

But what if biorefineries could produce their own tailored enzymes on-site? The good news is that they already can. With a little help, of course.

At VTT, we believe that on-site enzyme production is the way forward for two reasons: lower costs and the possibility to tailor the enzymes to specific raw materials and processes.

When it comes to costs, on-site production ensures a consistent supply while also cutting out the need for costly concentration, formulation, and transport. Instead, biorefineries are able to pump the liquid enzymes directly into the process as needed.

On-site production also overcomes the “one size fits all” challenge faced with commercially produced enzymes, which can’t be tailored to better suit a biorefinery’s specific raw material or production processes. With the capability to produce their own enzymes on site, biorefineries can find the perfect formula and develop a local product that delivers better results – all for less money.

The greater flexibility offered by on-site enzyme production should also enable new business models for processing other waste products or producing non-ethanol products, including those with smaller volumes than a typical first-wave biorefinery producing ethanol.

When it comes down to it, no one transports yeast to biorefineries to run fermentations, so why should enzymes be any different? As the majority of the world’s biomass is located in regions like South America, Sub-Saharan Africa, and Southeast Asia, the significant cost savings enabled by local supply mean that the shift towards on-site production will become reality in the not too distant future.

Learn more about our thoughts on onsite enzyme production by joining our upcoming webinar: https://makingoftomorrow.com/on-site-enzyme-production-to-cut-costs-in-biorefining/

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Simo Ellilä
Research Scientist
simo.ellila(a)vtt.fi

Corrosion in biomass power plants – prevent it or deal with it!

As the world moves towards low-carbon fuel solutions, the number of power plant boilers combusting biomass or recycled fuel steadily grows, with more than one thousand biomass boilers in Europe alone. Biomass boilers use various fuels, such as forest residue, wood and recycled wood, as well as agricultural crops like straw and other waste to energy materials.

One of the most serious problems biomass plants face is severe corrosion. In biomass boilers, corrosion comes from burnt fuels containing alkali metals, chlorine and other corrosive elements, and causes material wastage, tube failures, tube leakages, and a shorter boiler tubing lifetime. Worst-case scenario, corrosion leads to the emergency shutdown of your boiler, bringing huge economic and safety repercussions.

Putket

How can corrosion best be tackled?

Corrosion can be slowed or even prevented in power plant boilers. One way is to limit maximum temperatures and steam pressure. However, bringing down your plant’s heat and electricity production capacity will, by definition, lower its overall efficiency and profitability.

Chemical additives, like sulphur compounds, or tube material selection are other possible ways to slow or even prevent corrosion. However to my mind the most cost effective and reliable way to tackle corrosion is through nickel- and iron-based HVOF protective coatings. These high-alloyed materials can be applied typically as weld overlays or thermal spray coatings to increase the corrosion resistance of the lower cost load carrying base tube.

Pinnoite

Coatings to prevent corrosion

Backed by our long experience in thermal spray coatings, we’ve helped clients to select the most suitable commercially available materials or produce experimental powders to suit specific plant conditions. We can also optimize the coating parameters, especially for high velocity thermal sprays, and test them in harsh high-temperature corrosion conditions – both in laboratory simulations or in actual power plant conditions.

Coatings can be evaluated to perform on a scale from sufficient to excellent in conditions simulating biomass and recycled fuel combustion and in actual furnace conditions, as long as they are dense, well adhered to the substrate and their composition is accurately selected for the prevailing conditions.

As a case in point, thermally sprayed coatings in the EU project, NextGenPower, were evaluated both in molten salt tests in a laboratory and by corrosion and material assessment probes in one of the world’s largest biomass co-fired fluidized bed boilers in Pietarsaari, Finland. Optimization of the coating structure and fabrication of high-quality coatings was a key part of securing the high corrosion-resistant coatings that were developed as a result of this successful experiment.

I personally performed a public defence of this research in my dissertation. The coating experience and know-how that came from the NextGenPower case has been brought into the VTT ProperScan® service for your benefit, to help you avoid production losses, minimize risk, and increase the lifetime of your plant components, even in extreme temperature conditions.

Read more about VTT ProperScan® or my dissertation.

Maria Oksa VTT

Maria Oksa
Senior Scientist, Project manager

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